Photo of Quantum phase transition underpins superconductivity in copper oxides

Quantum phase transition underpins superconductivity in copper oxides

by Lindsay Jolivet Quantum Materials 22.02.2016

Physicists have zoomed in on the transition that could explain why copper-oxides have such impressive superconducting powers.

Settling a 20-year debate in the field, they found that a mysterious quantum phase transition associated with the termination of a regime called the “pseudogap” causes a sharp drop in the number of conducting electrons available to pair up for superconductivity. The team hypothesizes that whatever is happening at this point is probably the reason that cuprates support superconductivity at much higher temperatures than other materials — about half way to room temperature.

A phage diagram showing the cuprate's transition between charge density waves (CDW) and superconductivity.
A phage diagram showing the cuprate’s transition between charge density waves (CDW) and superconductivity.

“It’s very likely that the reason superconductivity grows in the first place, and the reason it grows so strongly, is because of that critical point,” CIFAR Senior Fellow Louis Taillefer (Université de Sherbrooke) says. The new findings are published in Nature.

Taillefer, the director of CIFAR’s program in Quantum Materials, collaborated with his team and CIFAR Cyril Proust (Laboratoire National des Champs Magnétiques Intenses), Doug Bonn, Walter Hardy and Ruixing Liang (all three University of British Columbia). The study combined the University of British Columbia’s expertise in making copper-oxide materials known as cuprates, the Université de Sherbrooke’s expertise at probing them, and the powerful magnetic fields produced at the Toulouse lab.

Their work is part of a global effort to harness superconductivity — the transmission of electricity with zero resistance in certain materials — to greatly improve power efficiency in many technologies. Cuprates are the most promising materials for that purpose right now, but the community is faced with a formidable physics problem: understanding the mysterious “pseudogap” phase.

“That’s been the debate for 20 years — what is going on in the pseudogap phase?” says Taillefer.

The mystery has remained unsolved for so long mainly because when superconductivity kicks in, it becomes difficult to study what behaviours are taking place beneath it. With a magnetic field two million times that of the Earth’s, the team of scientists managed to wipe out superconductivity in cuprate samples and look closely into the pseudogap phase at temperatures near absolute zero (- 273 C).

At the point of instability where the pseudogap sets in, the electronic structure of cuprates undergoes a radical change. The number of available electrons plummets six-fold. This marks a quantum phase transition — a fundamental change of behaviour within the material.

The scientists believe this new work will create a major shift in the focus of future research, and will lead to a new understanding of the properties of superconductors. Taillefer says this finding points the way to discovering the nature of the critical point and its fluctuations, and then exploring how to make superconductivity work at room temperature.

The discovery follows intense research on the pseudogap mystery, after the same group of CIFAR researchers discovered the first signs of strange behaviour by observing quantum oscillations in 2007. “The development at Toulouse of very low noise measurements, crucial for the discovery of quantum oscillations in 2007, and now recently the design and construction of our 90 T magnet, together opened up a new window of capability, allowing us to look directly at the pseudogap critical point,” says Cyril Proust.

CIFAR Associate Fellow Subir Sachdev (Harvard University) says the findings validate some of his recent theoretical research and set a clearer direction for future investigation that zooms in on this critical point.

“This gets me very excited about working on the theory of such a critical state,” Sachdev says. “The new experiments really sharpen the picture.”

Taillefer says the research would not have been possible without CIFAR fostering collaboration on quantum materials within Canada and internationally. “It’s really a pure CIFAR story,” he says. Bonn adds that CIFAR’s long-term support of collaborations on materials development and many experimental techniques to study the materials has advanced the field. “The UBC-Sherbrooke collaboration is a particularly successful and long-running example, with each new experimental discovery pushing harder on further development of the materials samples used in the experiments,” he says.

“This breakthrough is an example of how sustained, global collaboration that brings together diverse expertise from across the world is the most powerful way to advance science and address important sustainability challenges,” says CIFAR President and CEO Dr. Alan Bernstein.

“This discovery proves once more the extremely high quality of Prof. Taillefer’s research. He and his team have contributed to our success in the inaugural competition of the Canada First Research Excellence Fund. This success is consolidated by the recent creation of the Quantum Institute,” states Prof. Jacques Beauvais, Vice-President, Research, Innovation and Entrepreneurship.

The Université de Sherbrooke and the University of British Columbia received a total of $100 million from the Canada First Research Excellence Fund last year to support research on quantum materials and quantum technologies.

Image above: The magnet at the Laboratoire National des Champs Magnétiques Intenses that produces a magnetic field two million times that of the Earth’s. Credit: William Knafo.

Leave a Comment

Your email address will not be published.

You may use these HTML tags and attributes: <a href="" title=""> <abbr title=""> <acronym title=""> <b> <blockquote cite=""> <cite> <code> <del datetime=""> <em> <i> <q cite=""> <s> <strike> <strong>

Related Ideas

Quantum Materials | News

Building stable qubits in diamonds

The potential power of a quantum computer comes from the qubit – a unit of information which quantum physics allows...

Bio-inspired Solar Energy | Commentary

Canada’s role as a clean tech research leader

Last month I met with Dr. Mario Molina, the chemist who more than 40 years ago made the Nobel Prize-winning...

Cosmology & Gravity | Commentary

Making waves in interdisciplinary research

One hundred years ago, Albert Einstein predicted that gravity could propagate in the form of gravitational waves, bending the fabric...

Quantum Materials | News

Probing the symmetry of superconductivity at the atomic level

Electron orbitals can exhibit surprising and unexpected patterns in superconducting cuprates, according to the latest finding by Waterloo physicists David...